Bis[2-(2-furyl)-1-(2-furylmethyl)-1H-benzimidazole-κN 3]diiodidocadmium
نویسندگان
چکیده
In the title complex, [CdI(2)(C(16)H(12)N(2)O(2))(2)], the Cd(II) atom is located on a twofold rotation axis and is four-coordinated by two N atoms from symmetry-related 2-(2-fur-yl)-1-(2-furyl-meth-yl)-1H-benzimidazole ligands and two I atoms in a distorted tetra-hedral configuration. The benzimidazole rings in adjacent mol-ecules are parallel, with an average inter-planar distance of 3.486 Å. The I atom is disordered over two sites in a 0.85 (5):0.15 (5) ratio.
منابع مشابه
Dichloridobis[2-(2-furyl)-1-(2-furylmethyl)-1H-benzimidazole-κN 3]cadmium(II)
In the title complex, [CdCl(2)(C(16)H(12)N(2)O(2))(2)], the Cd(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from symmetry-related 2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole ligands and by two symmetry-related Cl atoms. Intra-molecular C-H⋯O hydrogen bonds stabilize the mol-ecular configuration. Adjacent mol-ecules are linked throu...
متن کاملTetra-μ-acetato-κ8 O:O′-bis{[2-(2-furyl)-1-(2-furylmethyl)-1H-benzimidazole-κN 3]copper(II)}
The title complex, [Cu(2)(CH(3)COO)(4)(C(16)H(12)N(2)O(2))(2)], forms a dimer of the paddle-wheel type located on a crystallographic inversion centre. The two Cu(II) atoms [Cu⋯Cu = 2.7254 (11) Å] are bridged by four acetate anions. The geometry of the polyhedron around the metal centre can be described as tetra-gonal-pyramidal derived from the calculation of the value τ = 0.0018. The apical pos...
متن کاملBis(1-benzyl-1H-benzimidazole-κN 3)dichloridozinc
In the title compound, [ZnCl2(C14H12N2)2], the Zn(II) atom exhibits a distorted tetra-hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviati...
متن کاملBis(μ-3-hydroxybenzoato)-κ2 O 1:O 3;κ2 O 3:O 1-bis[bis(1H-benzimidazole-κN 3)(3-hydroxybenzoato-κO)nickel(II)] bis(1H-benzimidazole-κN 3)bis(3-hydroxybenzoato-κO 1)nickel(II) hexahydrate
The title compound, [Ni(2)(C(7)H(5)O(3))(4)(C(7)H(6)N(2))(4)][Ni(C(7)H(5)O(3))(2)(C(7)H(6)N(2))(2)]·6H(2)O, is a mononuclear/dinuclear nickel(II) cocrystal, the two mol-ecular species inter-acting through hydrogen bonds that involve the uncoordinated water mol-ecules. In the mononuclear species, the Ni(II) ion, located on an inversion center, is coordinated by two 1H-benzimidazole (bzim) ligand...
متن کامل(1H-Benzimidazole-5-carboxylic acid-κN 3)(1H-benzimidazole-6-carboxylic acid-κN 3)silver(I) perchlorate
The reaction of 1H-benzimidazole-5-carb-oxy-lic acid with silver nitrate in the presence of perchloric acid under hydro-thermal conditions yielded the title complex, [Ag(C(8)H(6)N(2)O(2))(2)]ClO(4), which comprises of an [Ag(C(8)H(6)N(2)O(2))(2)] mononuclear cation and a perchlorate anion. The Ag(I) ion is coordinated by two N atoms from two different neutral 1H-benzimidazole-5-carb-oxy-lic aci...
متن کامل